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Angewandte Chemie International Edition
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Last updated about 23 hours ago
A Fixed‐Charge Interphase Synchronizes Ion Transport to Suppress Space‐Charge‐Driven Inefficiency Under Nanoliter Confinement
1 day ago
Electrochemical energy storage breaks down under extreme miniaturization, where interfaces and space-charge...
Transient Activation Windows Program Adaptive Photochemical Responses
1 day ago
Transient pH-dissipative dynamics create activation windows that temporally gate molecular photochemistry. Coupling...
Precision Switching and Coupled Motion in a [3]Rotaxane Molecular Machine
1 day ago
A [3]rotaxane, composed by two crown ether macrocycles and an axle presenting...
Direct Deaminative Alkynylation of Aliphatic Primary Amines
1 day ago
Aliphatic primary amines are ubiquitous, yet their direct application as alkylating agents...
Ion‐Driving Polymer Entanglement for Dynamic Organic Phosphorescence
1 day ago
Potassium ions programmatically bridged ether and sulfonic acid groups within κ-carrageenan, triggering...
An Adaptive Ionic Sieve: Flexible Hydrogen‐Bonded Organic Frameworks Decouple the Trade‐Off Between Zn Ions Desolvation and Mass Transfer
1 day ago
A flexible hydrogen-bonded organic framework based on C 3‑symmetric trigonal carboxyl ligands...
Pd/C‐Catalyzed Hydrogenation of CF3‐, CF2H‐, and CF2CO2Et‐containing Pyridines: A Robust Method for Highly Functionalized containing Piperidines
1 day ago
A robust and efficient method to access diversely functionalized fluorinated piperidines was...
Pulsed‐Laser Ablation for the Synthesis of High‐Entropy Alloy Aerogels Toward H2O2 Production and Water Decolorization
1 day ago
This work establishes a universal strategy for fabricating compositionally complex solid solution...
Oxygen Bridge‐Induced Spin‐State Engineering Enables Solvation‐Barrier‐Free Sulfur Redox Kinetics in Lithium‐Sulfur Batteries
1 day ago
Dynamic vibration of interfacial Mo-O-Co oxygen bridges triggers a directional electron flow...
Nickel‐Catalyzed 1,2‐Arylalkenylation of Unactivated Alkenes Enabled by a Native Hydroxy Group
1 day ago
Nickel-catalyzed 1,2-arylalkenylation of alkenyl alcohols with readily available alkenyl boronates and aryl...
Metal–Organic Framework‐Gated Biocatalysis Enables Triggered Depolymerization of Melt‐Processed Polyesters
1 day ago
Metal–organic framework gating functions as a molecular lock, enabling enzyme–MOF composites to...
One‐Pot CO2 Hydrogenation Coupled With In Situ Esterification for Polyester Monomers Production Over Single‐Atom Cuδ+‐Doped 1.8 Nm T‐ZrO2
1 day ago
One-pot tandem catalytic system integrates CO2 hydrogenation to CH3O* and its esterification...