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Angewandte Chemie International Edition
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Iridium‐Catalyzed Ionic Hydrogenation of Multi‐Aza Heterocycles
2 days ago
Saturated nitrogen-containing heterocycles are ubiquitous in bioactive molecules and are thus attractive...
Isosteric Engineering of Enzymes: Overcoming Activity–Stability Trade‐Offs by Site‐Selective CH → N Substitutions
2 days ago
Coupling biosynthetic noncanonical amino acid production with genetic code expansion enables site-specific...
Peptide‐Functionalized Hydroxypropyl Cellulose Mitigates Amyloid‐β Protein Induced Endothelial Leakiness and Enhances Cognitive Function in Alzheimer's Disease
2 days ago
The peptide functionalized hydroxypropyl cellulose conjugate (HPC-pet) sequesters Aβ oligomers (Aβo) to...
Chemoenzymatic Synthesis of Heparan Sulfate Oligosaccharides by a Covalent Catch‐and‐Release Approach
2 days ago
A glycan having a hydrazide tag enables chemoenzymatic synthesis of HS oligosaccharides...
Rational Tailoring of Hole‐Selective Self‐Assembly Monolayers Based on Sulfur‐Containing Heterocycles for High‐Performance Perovskite Solar Cells
2 days ago
This molecular engineering strategy introduces non-centrosymmetric self-assembled monolayers (SAMs), TP and BTP...
Chemoenzymatic Synthesis of Well‐Defined α(2,8)‐ and α(2,9)‐Linked Oligosialosides
2 days ago
Well-defined α(2,8)- and α(2,9)-linked oligosialic acids of different lengths can be prepared...
Interfacial Lewis Acid Chemistry Enabled by Mesoporous MOFs Toward High‐Performance Four‐Electron Zinc–Iodine Batteries
2 days ago
Here, we establish an interfacial Lewis acid chemistry based on mesoporous Zr-UiO-66...
Active Oxygenated Group‐Rich Polymer Electrolyte Synchronizing Bilateral Interfacial Stabilization and Accelerated Kinetics for High‐Performance Solid‐State Li–O2 Batteries
2 days ago
A polymerized glycidyl methacrylate (PGM)-based gel polymer electrolytewith abundant active oxygenated groups(e.g...
Octahedral–Tetrahedral Site Synergism in Spinel Oxides Enables 1700 h‐Stable Electrosynthesis of 2,5‐Furandicarboxylic Acid in Near‐Neutral Media
2 days ago
Asymmetric Ruoct/Nitet coordination in spinel Co3O4 enables cooperative surface hydroxylation and HMF...
Asymmetric Total Synthesis of (+)‐Ineleganolide
2 days ago
The structurally complex cembrane norditerpenoid (+)-ineleganolide has been synthesized by a route...
Unlocking Zn‐Ion Diffusion in Disordered Rocksalt Cathodes for Nonaqueous Zn‐Ion Batteries
2 days ago
Developing viable cathode materials for multivalent battery chemistries is challenging due to...
Nonmetallic Si Doping Constructs Cu2O/Co–O–Si Tandem Sites for Neutral Nitrate Reduction Electrocatalysis Toward Ammonia Recovery and Energy‐Integrated Applications
2 days ago
A tandem catalytic system featuring Cu2O and “Co–O–Si” interfacial sites is developed...