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Angewandte Chemie International Edition
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Last updated about 13 hours ago
Iterative Synthesis of Pentacene Derivatives with Continuous Boron–Oxygen Bonds
about 15 hours ago
An iterative synthetic strategy enables the controlled introduction of continuous multiple B–O...
Hydroxylamine Hydrochloride as Bifunctional Reagent for Aminochlorination of Alkenes via Iron Catalysis
about 15 hours ago
An iron-catalyzed, acid-promoted aminochlorination of unactivated alkenes was reported, employing hydroxylamine hydrochloride...
Interfacial Water Reorientation in Gadolinium‐Doped Ru/RuOx Heterostructures Boosts Alkaline Hydrogen Oxidation Electrocatalysis
about 15 hours ago
Embedding isolated Gd atoms into Ru/RuO x heterostructures reinforces the built-in electric...
Manipulating Heavy Halogenated Asymmetric Terminals Affords Regio‐Regular Hetero‐Fluorinated/Brominated Dual Asymmetric Acceptor With a Binary Photovoltaic Efficiency of 20.3%
about 15 hours ago
A regio-regular local hetero-dihalogenated terminal and global asymmetric molecular scaffold strategy is...
Boron‐Doping of a Macrocyclic Tetrafuran Framework Unveils an Expanded Porphyrinoid With Switchable (Anti)Aromaticity and Conformational Dynamics
about 16 hours ago
We disclose a novel boron macrocycle derived from the sustainable furan building...
Oxidation State Determines Solvent Structure Around a Manganese–Vanadium Polyoxometalate Water‐Oxidation Catalyst
about 16 hours ago
Oxidation state controls microsolvation in the polyoxometalate {MnV}n−$\{{\rm MnV}\}^{n-}$ water-oxidation catalyst in...
Dimeric Self‐Assembled Monolayer Materials for High‐Performance Perovskite and Perovskite/Organic Tandem Solar Cells
about 16 hours ago
The dimeric self-assembled monolayer material DPh-4PACz, featuring an enhanced molecular dipole moment...
Cs3Bi2Br9 Quantum Dots‐Driven Photogenerated Bromine Radical Relay Enables Efficient Cleavage of Cα/Cβ─O Bonds for Lignin Depolymerization
about 16 hours ago
A Cs3Bi2Br9 quantum dots photocatalyzed radical relay approach has been successfully implemented...
Electrolyte Covalent Organic Frameworks for Exceptional Potassium Ion Conduction
about 16 hours ago
One-pot polymerization of monomers with oligo(ethylene oxide) side chains of different lengths...
Protonation‐Triggered Fluorescence Switching in COF Membranes for the Selective and Rapid Detection of New Psychoactive Substances
about 16 hours ago
This work reports a novel sensing platform using an ozone-activated COF membrane...
Ligand‐Switched Regiodivergent Fluoroallylic Alkylation of Secondary Nitroalkanes via an Unusual Inner‐Sphere Pathway
about 16 hours ago
We disclose a ligand-controlled regiodivergent allylic alkylation of secondary nitroalkanes with gem-difluorocyclopropanes...
Precise Modulation of Excited‐State Energy Flow via Consecutive Twisted Intramolecular Charge Transfer (ConTICT) for Autophagy‐Blocking Photothermal Therapy
about 16 hours ago
Organic photothermal agents are limited by competitive energy pathways and sluggish excited-state...