Angewandte Chemie International Edition

Rhodium‐Catalyzed Enantioselective Synthesis of Planar‐Chiral Macrocycles via De Novo Isoquinoline Formation

about 12 hours ago

We report a highly efficient synthesis of planar-chiral macrocycles via CpRh(III)-catalyzed intramolecular...

Multi‐Scale Architecture Regulation of Hard Carbons for High‐Efficiency Sodium Storage Across Ambient and Subzero Conditions

about 12 hours ago

A multi-scale structural regulation strategy enables precise tailoring of hard carbon architectures...

Pyridine Into Pyrrole Transformation Induced Within the Confinement of the Macrocycle

about 13 hours ago

This work demonstrates the nontrivial reactivity of pyridine incorporated into a porphyrin...

Regulating Lithium Bond to Reduce Polysulfide Parasitic Reactivity for High‐Stability Lithium Metal Anode

about 13 hours ago

Weak cation interaction is proposed to mitigate the intrinsic lithium polysulfide parasitic...

Electron Cloud Polarization of Single‐Atom Cu Boosts Electrocatalytic Reduction of High‐ and Low‐Concentration CO2 to Methanol

about 13 hours ago

An efficient Cu single-atom catalyst (CuN3−C) with polar electron cloud enables high-rate...

Deciphering the Transition From Tunneling to Band‐Like Transport in Protein‐Templated Biohybrid Junctions

about 13 hours ago

Embedding atomically precise metal nanoclusters within a protein scaffold induces a metal-dependent...

Adhesive Photoinitiator Constructs Polymer Jackets on Enzymes: Direct, Release‐Free Cytosolic Delivery

1 day ago

A supramolecular adhesive photoinitiator, GuCD⊃BP-SH, overcomes a central dilemma in enzyme therapeutics...

Distinct Tunable In‐Plane Birefringence via Domain Manipulation in a 2D Metal Halide Ferroelectric

1 day ago

This work reports a distinct tunable in-plane birefringence via domain manipulation in...

Correction to “Dual‐Targeting Biomimetic Semiconducting Polymer Nanocomposites for Amplified Theranostics of Bone Metastasis”

1 day ago

Dual Chemical Looping/Catalytic Process for Alkylation of Benzene With Ethane and Propane Yielding Ethylbenzene and Cumene Over Copper‐Containing Mordenite

1 day ago

We report a dual chemical looping/catalytic process coupling alkane dehydrogenation with aromatic...

From Phenols to Proteins: One‐Pot Biosynthesis and Genetic Encoding of Chalcogen‐Containing Tyrosine Analogues

1 day ago

A one-pot enzymatic platform enables the biosynthesis and site-specific incorporation of chalcogen-containing...

Local Polarity Engineering via Unsaturated Cu–N3 Sites for Enhanced Iodine Redox Chemistry in Zinc‐Iodine Batteries

1 day ago

We engineer unsaturated Cu–N3 sites to create local polarized microenvironments on the...