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Angewandte Chemie International Edition
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Last updated about 11 hours ago
Chiral Spiro‐Scaffolded C(sp3),P‐Chelated Iridacycles: Direct Asymmetric Hydrogenation of β,β‐Disubstituted Acrylate Salts
1 day ago
A novel class of stable chiral spiro-scaffolded C(sp3),P-chelated iridium catalysts has been...
Multiple Strong Ion–Dipole Interactions in Hierarchical Porous Polymer/Covalent Organic Framework Electrolytes Accelerating Stable and Efficient Ion Transport
1 day ago
We propose a design strategy for constructing a vinylene-linked covalent organic framework-based...
Functional and Network PHAs via Stereoselective Polymerization and Tailored Post‐Transformation
1 day ago
Catalyst-controlled stereoselective (co)polymerization of functionalized lactones produces vinyl-, allyl-, and propargyl-functionalized PHAs...
A Diammonium‐Based Non‐Dion‐Jacobson Phase 2D Perovskite With High Durability for Efficient and Stable 2D/3D Perovskite Solar Modules
1 day ago
Unlike traditional Dion-Jacobson or Ruddlesden–Popper architectures, (3,3-MDPDA)PbI4 features two layers of V-shaped...
Covalent Borane‐Thiourea Organocatalyst for Stereoselective Ring‐Opening Polymerization
1 day ago
Here we describe a covalent borane–thiourea organocatalytic system that overcomes the intrinsic...
Cross‐Interface Quasi‐Tandem Catalysis Over Amorphous Oxide‐Metal Junctions Steers CO2 Electroreduction Toward C3 Products
1 day ago
Defect-rich amorphous ZrO2 forms a unified oxide-metal interface with Ag and Cu...
Sustainable Electrochemical Valorization of Sulfite in Industrial Wastewater Into Sulfonate‐Based Molecules
1 day ago
An electrocatalytic CNT-based membrane incorporating commercial Ni nanoparticles enables continuous upgrading of...
Emergence of Chiral Defective Pores Through Chiral Linker Exchange in Nonchiral MOFs for Enantioselective Recognition
1 day ago
Chiral recognition remains challenging due to minimal property differences. This work develops...
A Novel Class of “Super‐Strained” Spiro Heterocycles: Gateway to 1‐Azaspiro[3.3]heptane Derivatives, and Biological Validation
1 day ago
A new class of “super-strained” spiro heterocycles—spirocyclic 1-azabicyclo[1.1.0]butanes—was synthesized via insertion of...
Confined Cationic Covalent Organic Cages Enable Oxidant‐Free Hofmann−Löffler−Freytag/Cyclization Sequences
1 day ago
Confined cationic covalent organic cages promote oxidant-free Hofmann–Löffler–Freytag/cyclization sequences through dynamic host–guest...
Engineering Orbital Hybridization via Coordination and Charging Modulation Toward Efficient and Stable Fe Single‐Atom Catalysts for Superior Oxygen Reduction
1 day ago
We report a strategy that integrates S dopants in the second coordination...
Measuring Local Exothermic Effects During the Oxidative Coupling of Methane Using Operando Luminescence Thermometry
1 day ago
Operando luminescence thermometry shows that the local catalyst temperature can exceed the...