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Angewandte Chemie International Edition
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Last updated about 13 hours ago
π‐Radical Cascades to Peri‐Fused Triangulene Dimers
about 18 hours ago
We demonstrate the potential of open-shell molecular graphene fragments as synthons for...
Unlocking Catalyst Activation as a Critical Bottleneck in Cross‐Coupling Reactions: Room‐Temperature Couplings of Weak Nucleophiles Enabled by [Pd(1‐MeNAP)TFA]2 Precatalysts
1 day ago
In many Pd-catalyzed cross-couplings, catalyst performance has been found to be limited...
A Bioinspired Approach toward the Complex Cyclotaxane Taxpropellane
1 day ago
A bioinspired semisynthesis of a C1,C7-oxygenated taxpropellane analogue 18 from 10-DAB (2)...
Structure–Selectivity Relationship Study of IDPi Using Fragment and Remote Site Descriptors
1 day ago
Aryl fragment and remote site descriptors were developed for imidodiphosphorimidate (IDPi) and...
Polyethylene as a Hydrogen Source for C─O Bond Cleavage Via Transfer Hydrogenation
1 day ago
Utilizing PE as an inexpensive hydrogen source, the acidic zeolite-catalyzed transfer hydrogenation...
Facile B–N Covalent Bond Fusion in N,N′‐Diaryldihydrophenazines: Achieving Efficient Narrowband Electroluminescence and Controlled Redox Activity
1 day ago
A lithium-free, highly efficient one-pot NH-directed borylation strategy affords dihydrophenazine nanographene segments...
Role of Water in Low‐Temperature CO2 Reduction at Defect‐Rich TiO2
1 day ago
Our results highlight the potential of reduced titania as a noble metal-free...
AND‐Logic‐Gated Aptamer Switch for Precise Targeting and Regulation of RNA G‐Quadruplexes
1 day ago
An AND-logic-gated aptamer switch enables tumor-selective activation of RNA G-quadruplex (rG4)-targeting function...
Li2CO3‐Derived Low‐Cost Li2S for Sulfide Solid Electrolytes Exceeding 11 mS cm−1
1 day ago
We develop a scalable low-cost route to high-quality Li2S from industrial benchmark...
BIBOP‐Catalyzed Asymmetric Staudinger/aza‐Wittig Reaction: Unified Syntheses of (–)‐Minfiensine and (+)‐Aspidophylline A
1 day ago
A unified approach has been developed to construct the common tetracyclic skeletons...
Adaptive Restructuring toward Intrinsically Stable Rh Catalyst during Water–Gas Shift Reaction
1 day ago
Atomically dispersed Rh on CeO2 spontaneously evolves into thermodynamically stable Rh3(CO)4 clusters...
Constructing Durable High‐Voltage PVDF‐Based Solid‐State Lithium Metal Batteries via an All‐in‐One Design
1 day ago
An “all-in-one” strategy is proposed to concurrently induce a β-phase polymer matrix...