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Angewandte Chemie International Edition
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Last updated about 11 hours ago
Beyond the Pre‐Equilibrium Approximation: Consequences of Elementary Step (Ir)reversibility on the Mechanistic Interpretation of Tafel Slope
1 day ago
The Tafel slope is a key descriptor of charge transfer kinetics in...
A Circular and Tacticity‐Independent Crystalline Mono‐Substituted Nylon‐6 Platform: Unexpected Large Positional Effects on Crystallizability and Performance
1 day ago
Methyl substitution positions on the nylon-6 backbone markedly affect crystallizability, thermomechanical properties...
Fused‐Ring Acceptor–π–Acceptor Architecture Enables Near‐Infrared‐Absorbing Mesoporous Covalent Organic Frameworks for Enhanced H2O2 Photosynthesis
1 day ago
Fused-ring acceptor–π–acceptor COFs are designed and synthesized. They feature mesoporous crystalline structures...
Machine Learning Accelerates Crystallization for Structure Determination
1 day ago
Single-crystal X-ray diffraction (SCXRD) is often constrained by the difficulty of obtaining...
Enantioselective C–H Functionalization Reactions Enabled by Cobalt(III)‐Centered Chiral Pockets
1 day ago
The stereoselective recognition of three-dimensional substrates remains a challenge. A chiral pocket...
β‐Ketoenamine Porous Organic Cage Membranes Through Hydrogel‐Induced Shielding for Efficient Ion Sieving
1 day ago
Kevlar hydrogel is capable of storing high-concentration diamines that facilitate the formation...
Anthraquinone‐Based Electron Reservoir‐Pump Photosensitizer Generating Radical Ion Pairs for Metabolism‐Targeted Photodynamic Therapy
1 day ago
We reported an anthraquinone-based single-component photosensitizer AQTPE engineered via an electron reservoir-pump...
Anomeric‐Effect‐Guided Saturated Weakly Solvating Electrolytes for Ultrastable High‐Voltage Sodium Metal Batteries
1 day ago
A class of saturated weakly solvating electrolytes (SWSEs) based on the ether...
One‐Step Radical‐Intensified Selective Etching (RISE) Strategy for High‐Yield Synthesis of Monolayer MXene with Tailored Nanoholes
1 day ago
Radical-intensified selective etching (RISE) delivers monolayer MXenes with >80% yield in just...
Catalyst‐Controlled Chemodivergent Carbene Transfer Reactions With Bicyclo[1.1.0]butane‐Derived Acceptor Metallocarbenes
1 day ago
Herein, carboxamide-functionalized bicyclo[1.1.0]butanes are introduced as versatile carbene precursors that generate acceptor-type...
Solar‐Driven Ammonia Synthesis From Nitrate Reduction Paired With CO2 Capture for Sustainable Agriculture via a Robust CuPd Heterojunction
1 day ago
Laser-assisted synthesis of CuPd amorphous/crystalline heterojunction demonstrates >80% Faradaic efficiency for nitrate-to-ammonia...
Ordered Ba2EuIrO6 Double Perovskite With Active Ir─Obri─Eu Unit for Enhanced Electrocatalytic Oxygen Evolution in PEMWE
1 day ago
A low-Ir-loading material of an ordered Ba2EuIrO6 double perovskite with Ir─Obri─Eu unit...