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Angewandte Chemie International Edition
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Last updated 1 day ago
Chlorination‐Driven BODIPY Fluorescent Probes for the Selective Monitoring of Myeloperoxidase Activity in Cells and Inflamed Mouse Models
2 days ago
A meso-carboxamide-substituted BODIPY fluorescent probe reports myeloperoxidase (MPO) activity via electrophilic chlorination...
Precise Manipulation of Discrete Lanthanide Complexes Vitrification via Flexible Chains and Rigid Modules: Accessing Near‐Unity Photoluminescence Quantum Yields, Upconversion Luminescence, and Ultra‐Bright X‐ray Scintillators
2 days ago
Aiming at the challenge that zero-dimensional lanthanide complexes hardly form glasses via...
Reusable Polyphenol Building Blocks Enable Recyclable Epoxy‐Amine Thermosets via Methanolysis
2 days ago
A biobased epoxy–amine platform was developed using functional building blocks derived from...
Hydrogen‐Bonding Order Associated With Radical Delocalization in Layered Organic Cathode Materials
2 days ago
“TAQ” and TAPT share the same pyrazine-based molecular structure but differ in...
Stepwise Multidimensional Asymmetric Design of Dimeric Acceptors Enables Simultaneous Ordered Packing and High PLQY for High‐Efficiency Organic Solar Cells
1 day ago
Stepwise multidimensional asymmetry engineering yields dimeric acceptors C1, C2, and C3. It...
Beyond Nature's Blueprint: Macrocyclic Peptides Containing Unnatural Amino Acids in Therapeutic Development
1 day ago
Strategic incorporation of unnatural amino acids transforms macrocyclic peptides into drug-like molecules...
Orbital Hybridization Dominates the Enhanced Polarization Response Arising From Interlayer Coupling in Ti3C2Tx MXene
1 day ago
This work elucidates the interlayer coupling in two-dimensional materials, which is predominantly...
Ring‐Retentive Allylation of Cyclopropanols Through Interception of Enolized Homoenolates by π‐Allylpalladium
1 day ago
Cyclopropanols undergo palladium-catalyzed, zinc-mediated allylation with allyl acetates: the ring opens transiently...
Europium Macrocyclic Complexes With Rigid High‐Symmetry Coordination Geometry for High‐Voltage and Durable Neutral Aqueous Redox Flow Batteries
1 day ago
A rigid macrocyclic DOTA framework creates a highly symmetric coordination environment that...
Solid‐State‐Enabled Three‐Stage Delithiation Pathway of Li5FeO4 for Silicon‐Based All‐Solid???State Batteries
1 day ago
A solid-state reaction environment activates low-potential lattice-oxygen redox below 3.7 V in...
Ultrafast Nuclear Rearrangement Governs Excited‐State Radial π‐Conjugation and Electron Transfer Dynamics in Organic Nanoring
1 day ago
Time-resolved impulsive stimulated Raman spectroscopy directly reveals the nuclear motions governing excited-state...
The Stubborn Persistence of Toxic Solvents in Chemical Synthesis
1 day ago
Solvent choice is governed by precedent more than chemistry. Analysis of 1.3...