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Angewandte Chemie International Edition
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Thermodynamic Compensation of Surface Hydroxyl Moieties in Reduced Polyoxometalates Translates to Deviations in the Mechanism of Proton–coupled Electron Transfer
1 day ago
The change in the central atom in the series of vanadium-doped Keggin-type...
Water‐Splitting “Without Water”: Splitting of the Crystallised Water of Hydrated Salts
1 day ago
Unlike liquid water, the structural and molecular properties of water molecules embedded...
Photoenzymatic Aliphatic C─Br Activation for Enantioselective Synthesis of γ‐Stereogenic Nitriles from Alkenes
1 day ago
The present work showcases a photoenzymatic platform using bromoacetonitrile as a practical...
On the Origin of Substrate Specificity of Enzymes from the Amidohydrolase Superfamily
1 day ago
Comprehensive analyses of two enzyme classes from the amidohydrolase superfamily (AHS) revealed...
Monitoring Enzyme Clustering in a Highly Crystalline Metal–Organic Framework by Small‐Angle Neutron Scattering
2 days ago
Small-angle neutron scattering was used to probe porosity changes in the high-q...
Ruthenium‐Catalyzed Electrochemical Ketone Hydrogenation to Secondary Alcohols with High Activity and Selectivity Under Ambient Conditions
2 days ago
Systematic screening identifies Ru nanoparticles on carbon black (RuNP/C) as an efficient...
A Modularly Integrated Chiral Cavitand
2 days ago
A highly modular, three-component coassembly system has been developed that achieves high-fidelity...
Photoswitchable Peptides as Molecular Tools to Encode Structural Order and Disorder in Intracellular Assemblies
2 days ago
We present a photoswitchable peptide conjugate which exhibits isomerism-dependent self-assembly: the planar...
Regio‐Divergent and Stereo‐Controlled Alder‐Ene Reaction: Harnessing the Unique Electronic and Steric Properties of B(MIDA) Moiety
2 days ago
Controlling the regioselectivity of Alder-ene reactions with unsymmetrical alkynes remains a significant...
Co‐Assemblies Regulate the Catalytic Activity of Peptide Fibrils
2 days ago
Catalytic self-assembling peptides (cSAPs) form fibrils that catalyze the retro-aldol reaction of...
18F‐Radiopharmaceutical Diversification Enabled by Deaminative Cross‐Electrophile Couplings
2 days ago
A general Ni-mediated (C)sp2 –(C)sp3 cross-coupling expedites access to 18F-radiopharmaceuticals, essential for...
A 4+3 β‐Ketoenamine‐Linked Covalent Organic Framework Membrane for High‐Performance Film‐Based Fluorescent NO2 Sensor
2 days ago
This study develops a novel fluorescent NO2 sensor using a newl fabricated...