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Angewandte Chemie International Edition
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Last updated about 21 hours ago
Loose Al3+ Solvation Aggregates Enable Reversible Aluminum Anodes in Chlorine‐Free Electrolyte
1 day ago
Loose solvation aggregates (LAGs), enabled by TPFPB-assisted solvation regulation, facilitate rapid ion...
31P Solid‐State NMR‐Enabled Development of a Pt/Aluminum Tripolyphosphate Catalyst for Selective C─O Bond Hydrogenolysis of Phenols
1 day ago
31P solid-state nuclear magnetic resonance analysis revealed the presence of aluminum tripolyphosphate...
Sono‐Tribocatalytic Whole Tumor Cell Vaccine Enables Ultrasound‐Controlled Immune Boosting for Enhanced Anti‐Tumor Immunity
1 day ago
We report a single-dose whole tumor cell vaccine enabled by intracellular sono-tribocatalytic...
Cluster‐Directed Solvation Engineering for Dual‐Interface Stabilized Gel Polymer Electrolytes Enabling High‐Voltage and Fast‐Charging Lithium‐Ion Batteries
1 day ago
High-voltage GPEs that combine fast Li+ transport, thermal robustness, and dual-interface stability...
Hypothesis‐and‐Refinement Learning of Organic Structures From Multimodal Spectroscopic Data
1 day ago
A multimodal hypothesis-and-refinement framework integrates IR, UV, HRMS, and 1D and 2D...
Trace Amorphous FeOx Steers O2 Activation From Charge Transfer to Energy Transfer for Singlet‐Oxygen‐Mediated Biomass Valorization
1 day ago
We show that trace ultrasmall amorphous FeOx steers selective aerobic photocatalysis from...
A Mechanical sp2‐Jail for C60 Fullerene
1 day ago
A rigid bisporphyrin receptor with an exceptionally compact 3D cavity functions as...
1,2‐Bis(boronate) Arenes by Borylation Directed Borylation
1 day ago
Boron electrophiles derived from tetrabromo-pyrazaboles and AlCl3 affect the regioselective vicinal double...
Access to N‐Fused Acyl Aziridines for Modular Difunctionalization of Olefins by Ruthenium‐Catalyzed Nitrenoid Transfer
1 day ago
Ruthenium catalysis enabled access to previously elusive N-fused acyl aziridines and their...
A Conserved Isoleucine Gates the Diffusion of CO and O2 to the Active Site of NiFe CO‐Dehydrogenase
1 day ago
A combination of protein film electrochemistry and site-directed mutagenesis shows that isoleucine...
Late‐Stage Annulative Imidazolation for Expanding Histidine‐Analogous Side Chains in Peptides and Proteins
1 day ago
Re-engineering the classic Debus–Radziszewski reaction enables highly chemoselective, multicomponent N-imidazolation of complex...
Rational Construction of Fluoride Crystals With Record Birefringence via Water‐Regulated Hydrogen‐Bond Network Reconfiguration
1 day ago
The water-mediated hydrogen-bond network reconstruction strategy effectively alleviates the inherent trade-off between...