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Angewandte Chemie International Edition
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Last updated about 16 hours ago
Labile photo‐induced free radical in alpha‐ketoglutaric acid: a universal endogenous polarizing agent for in vivo hyperpolarized 13C magnetic resonance
about 18 hours ago
Hyperpolarized (HP) 13 C magnetic resonance enables non-invasive probing of metabolism in...
Chiroptical Switching and Quantitative Chirality Sensing with (Pseudo)halogenated Quinones
about 20 hours ago
We report that (pseudo)halogenated quinones react with chiral amines, amino alcohols and...
Rhodium‐Catalyzed Atroposelective Access to Axially Chiral Olefins via C‐H Bond Activation and Directing Group Migration
about 22 hours ago
Axially chiral open-chain olefins represent an underexplored class of chiral platform. In...
Generation of a [[EQUATION]]‐Bonded Isomer of [P4]4− by Aluminyl Reduction of White Phosphorus and its Ammonolysis to PH3
about 22 hours ago
By employing the highly reducing aluminyl complex [K{(NON)Al}] 2 (NON = 4,5-...
A Modular Approach to the Antifungal Sphingofungin Family: Concise Total Synthesis of Sphingofungin A and C
about 23 hours ago
Sphingofungins are fungal natural products known to inhibit the biosynthesis of sphingolipids...
Tetraaryldiborane(4) Can Emit Dual Fluorescence Responding to the Structural Change around the B–B Bond
about 23 hours ago
We report the successful synthesis of tetramesityldiborane(4) (Mes 4 B 2 )...
Construction of NH‐unprotected spiropyrrolidines and spiroisoindolines by [4+1] cyclizations of γ‐azidoboronic acids with cyclic N‐sulfonylhydrazones
about 23 hours ago
The reactions of N -sulfonylhydrazones derived from cyclic ketones with γ-azidopropylboronic acid...
Enantioselective Synthesis of Chiral Carboxylic Acids from Alkynes and Formic Acid by Nickel‐Catalyzed Cascade Reactions: Facile Synthesis of Profens
1 day ago
We report a stereoselective conversion of terminal alkynes to α-chiral carboxylic acids...
Visible‐Light‐Induced Selective Photolysis of Phosphonium Iodide Salts for Monofluoromethylations
1 day ago
Simple and selective synthesis of fluoromethylated alkenes, heterocycles, enamines and heteroarenes by...
Dual‐targeting Circular Aptamer Strategy Enabled Recognition of Different Leukemia Cells with Enhanced Binding Ability
1 day ago
Currently, the broad use of monovalent aptamers in oncology faces challenges, including...
Stabilization of the Elusive Antimony(I) Cation and Its Coordination Complexes with Transition Metals
1 day ago
The elusive SbI cation has been stabilized by the 5,6-bis(diisopropylphosphino)acenaphthene ligand (see...
Estela Climent
1 day ago
“My favorite thing about my lab group is how multicultural and multidisciplinary...