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Angewandte Chemie International Edition
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Last updated about 1 hour ago
Heavy‐Atom Tunneling at Room Temperature Revealed by Instanton Theory
1 day ago
Usually, tunneling does not play a significant role in chemical reactions except...
Aromaticity Regulation in Isostructural Metal‐Organic Frameworks for Propyne Storage and Propylene Purification
1 day ago
A pyrene-decorated MOF shows highly efficient alkene purification and propyne storage ABSTRACT...
Noncovalent‐Interaction–Driven Single‐Molecule Exchange Enables Enantiomer Discrimination of Selected Amino Acids in a Nanopore
1 day ago
Dynamic molecular exchange within a CB[7]-confined nanopore nanocage amplifies subtle stereochemical differences...
Engineering van der Waals Heterojunctions Within a 2D Hydrogen‐Bonded Organic Framework for Boosting CO2 Electroreduction
1 day ago
Interlayer van der Waals donor–acceptor (D–A) heterojunctions in hydrogen-bonded organic framework PFC-45-Co...
Oleylamine‐Assisted Construction of Bi‐Bi2O2CO3 Heterojunction With a Self‐Release‐Replenishing Mars‐van Krevelen‐Type Mechanism for Efficient CO2 Electroreduction
1 day ago
A self-release-replenishing Bi-BOC cycle enables lattice-mediated intermediate supply, alleviates gaseous CO2 transport...
Complete Pathway Refactoring and Combinatorial Biosynthesis of Anthracyclines for Modulation of Histone Eviction and DNA Damage Bioactivities
1 day ago
A synthetic biology platform was established for the complete refactoring of complex...
Low‐Threshold Red Lasing in Diketopyrrolopyrrole‐Based Organic Semiconductor Films
1 day ago
Low-threshold organic semiconductor lasers (OSLs) in the red region are achieved using...
Biomimetic Confined Crystallization of Large‐Sized Single‐Crystalline Multicomponent Mesoporous Metal Oxides
about 18 hours ago
Inspired by biomineralization, we developed a biomimetic confined crystallization strategy that overcomes...
Second‐Sphere Aromatic Substitutions That Tune H‐Atom Transfer Reactivity Observed for a Series of S = 1 Nonheme FeIV=O Complexes: An Enthalpy‐Entropy Compensation Effect
about 18 hours ago
A series of oxoiron(IV) complexes was synthesized to determine the impact of...
Tandem Interphase Design Achieves Two‐Year Cycling of Aqueous Zinc Metal Batteries Under Extreme Conditions
about 18 hours ago
We propose a scalable outer-hydrophilic/inner-zincophilic (OHIZ) tandem structure SEI for zinc anodes...
Hierarchical Accessibility and Framework‐Al Organization in Ultra‐High‐Silica ZSM‐5 Enable Efficient Cracking of Polyolefin Waste to Light Olefins
about 6 hours ago
An ultra-high-silica hierarchical ZSM-5 zeolite, constructed using cetyltrimethylammonium bromide (CTAB) and tert-butanol...
Fluoroalcohol‐Mediated Solvation for Self‐Assembled Molecules Anchoring Optimization Toward High‐Performance Organic Solar Cells and Flexible Module
about 5 hours ago
A fluoroalcohol-mediated solvation strategy is developed to enhance the thermodynamic driving force...