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Angewandte Chemie International Edition

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Last updated about 16 hours ago

Labile photo‐induced free radical in alpha‐ketoglutaric acid: a universal endogenous polarizing agent for in vivo hyperpolarized 13C magnetic resonance

about 18 hours ago

Hyperpolarized (HP) 13 C magnetic resonance enables non-invasive probing of metabolism in...

Chiroptical Switching and Quantitative Chirality Sensing with (Pseudo)halogenated Quinones

about 20 hours ago

We report that (pseudo)halogenated quinones react with chiral amines, amino alcohols and...

Rhodium‐Catalyzed Atroposelective Access to Axially Chiral Olefins via C‐H Bond Activation and Directing Group Migration

about 22 hours ago

Axially chiral open-chain olefins represent an underexplored class of chiral platform. In...

Generation of a [[EQUATION]]‐Bonded Isomer of [P4]4− by Aluminyl Reduction of White Phosphorus and its Ammonolysis to PH3

about 22 hours ago

By employing the highly reducing aluminyl complex [K{(NON)Al}] 2 (NON = 4,5-...

A Modular Approach to the Antifungal Sphingofungin Family: Concise Total Synthesis of Sphingofungin A and C

about 23 hours ago

Sphingofungins are fungal natural products known to inhibit the biosynthesis of sphingolipids...

Tetraaryldiborane(4) Can Emit Dual Fluorescence Responding to the Structural Change around the B–B Bond

about 23 hours ago

We report the successful synthesis of tetramesityldiborane(4) (Mes 4 B 2 )...

Construction of NH‐unprotected spiropyrrolidines and spiroisoindolines by [4+1] cyclizations of γ‐azidoboronic acids with cyclic N‐sulfonylhydrazones

about 23 hours ago

The reactions of N -sulfonylhydrazones derived from cyclic ketones with γ-azidopropylboronic acid...

Visible‐Light‐Induced Selective Photolysis of Phosphonium Iodide Salts for Monofluoromethylations

1 day ago

Simple and selective synthesis of fluoromethylated alkenes, heterocycles, enamines and heteroarenes by...

Dual‐targeting Circular Aptamer Strategy Enabled Recognition of Different Leukemia Cells with Enhanced Binding Ability

1 day ago

Currently, the broad use of monovalent aptamers in oncology faces challenges, including...

Stabilization of the Elusive Antimony(I) Cation and Its Coordination Complexes with Transition Metals

1 day ago

The elusive SbI cation has been stabilized by the 5,6-bis(diisopropylphosphino)acenaphthene ligand (see...

Estela Climent

1 day ago

“My favorite thing about my lab group is how multicultural and multidisciplinary...