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Angewandte Chemie International Edition
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Last updated about 16 hours ago
Redirecting Regioselectivity in Cytochrome P450 ApPT for B‐Ring Functionalization of Pentacyclic Triterpenoids
1 day ago
A semi-rationally engineered P450 disrupts the native radical transfer pathway to achieve...
Adenylation Domain Engineering Enables Biosynthesis of an Improved Polymyxin Antibiotic
1 day ago
To enable incorporation of l-2-aminodecanoic acid into polymyxin by fermentation, a single...
Fluorinated Self‐Assembled Monolayers for Highly Reversible Anode‐Free Zinc Batteries
1 day ago
Stepwise fluorinated self-assembled monolayers (CPM → MPM → DMPM) construct a dual-functional...
Discovery and Characterization of Conserved N‐Oxide‐Forming Function of FAD‐Dependent Monooxygenases for Fungal Prenylated Indole Alkaloid Biosynthesis
1 day ago
PldC is the first identified fungal bifunctional FAD-dependent monooxygenase that mediates sequential...
Active Electrochemical Regulation Strategies Based on Dynamic Response Mechanisms for Secondary Batteries
1 day ago
Electrochemical regulation strategies are integrated with fundamental electrochemical theory and advanced engineering...
Catalyst–Electrolyte Synergy Enables Ultrafast and Long‐Life Two‐Electron Aqueous Zinc–Iodine Batteries
1 day ago
A chloride-rich ZnCl2 electrolyte stabilizes iodine species but leaves multistep iodine conversion...
Engineering Directional Ion Transport Channels in Three‐Dimensional Covalent Organic Frameworks for High‐Performance Sodium‐Ion Batteries
1 day ago
Construction of 3D COF with precisely oriented C═O active sites within the...
1‐Azabicyclo[1.1.0]butanes (ABBs) on the Map: Mechanistic Pathways for Catalytic Ring Opening and Functionalizations
1 day ago
Catalytic strain-release ring opening and functionalizations of 1-azabicyclo[1.1.0]butanes (ABBs) represent a promising...
High Entropy Regulation of Electrostatic Repulsion and Structural Design in Layered Oxide Cathodes for Sodium‐Ion Batteries
1 day ago
This review elucidates how entropy strategies regulate electrostatic repulsion and structural evolution...
Toward Cell‐Specific Molecular MRI: Modulating Chemical Exchange Saturation Transfer Contrast With Manganese
1 day ago
Manganese-modulated chemical exchange saturation transfer (CEST) MRI, Manga CEST, leverages intracellular Mn2...
Heme Peroxo Reaction Intermediates: Mimicking Biological Structure and Reactivity With Synthetic Model Systems
2 days ago
Despite the traditional classification as sluggish oxidants, heme peroxo intermediates have recently...
Synergetic Dopant and Additive Engineering of Hole Transporter for Outdoor‐Stable Perovskite Solar Modules
2 days ago
A synergistic Zn(TFSI)2/vinylene carbonate (VC) strategy is developed to oxidize spiro-OMeTAD hole-transport...