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Angewandte Chemie International Edition

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Highly Enantio‐ and Diastereoselective Synthesis of Tetrahydrofuran Frameworks via Chiral Lewis Acid‐Catalyzed Formal [3+2] Cycloaddition of Allylsilanes

2 days ago

The first catalytic asymmetric formal [3+2] cycloaddition of allylsilanes delivers cis-2,5-disubstituted tetrahydrofuran-3-ones...

Na–Fe–P Stoichiometry‐Driven Heterostructure Design With a P2O7‐Rich Buffering Phase for Stable NASICON‐Type Sodium‐Ion Cathodes

2 days ago

An NFPP/N3.12F2.44PO heterostructure is designed to enhance the structural stability of the...

Borate‐Enabled, Scalable Copper Catalysis for Suzuki–Miyaura Cross‐Coupling of Pyridylborons With Unactivated Alkyl Bromides

2 days ago

Described herein is a borate‑enabled copper‑catalyzed Suzuki–Miyaura coupling of challenging pyridylborons with...

Anion‐Managing Biomimetic Electrolyte Based on Fluorinated COF Recognition and Hyperbranched Polyamidoamine Capture for Practical Lithium–Metal Batteries

2 days ago

The composite polymer electrolyte based on covalent organic framework (COF) and hyperbranched...

Mechanistically Guided Combinatorial Coding Based on Strand Displacement Probes for Multiplex Pathogen Variant Discrimination

2 days ago

A mechanistically guided color-coding strategy enables scalable discrimination of genetic variants with...

[O─I─O]+ Halogen‐Bonded Complexes of Pyridine N‐Oxides

2 days ago

The missing puzzle of 3-center-4-electron halogen-bonded complexes viz. [O─I─O]+ of pyridine N-oxides...

Silicon‐Bridged Homocyclopentadienides: Metal‐Assisted Facile Ring Expansion of Cyclopentadienide by Transient Imino(Metallophosphino)Silylenes

2 days ago

We demonstrate the facile aromatic C─C bond cleavage of cyclopentadienide mediated by...

Reshaping Chiral Self‐Assemblies Through Alkyne‐Involved Click Chemistry

2 days ago

A Type II topochemical co-assembly was realized, where reaction products reorganize directionally...

Phosphor‐Sensitized Deep Blue Narrowband OLED Devices With EQE Over 40% by Using a Horizontal‐Oriented Host

2 days ago

A horizontal-oriented host with a linear geometry was developed, featuring positive potential...

Low‐Energy Photons in Radical Chemistry: From Deep‐Red to Near‐Infrared Radical Generation for Organic Synthesis

2 days ago

Low-energy photons from deep-red (DR) to near-infrared (NIR) light offer unique opportunities...