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Angewandte Chemie International Edition
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Last updated about 7 hours ago
Intermolecular Carbon–Carbon Naphthalene Coupling Involves a Radical Mechanism Driven by Cytochrome P450 in Alternaria alternata
1 day ago
1,8-DHN is an important intermediate to form complex aromatic ring systems. Phenol-coupling...
Carbohydrate‐Directed Labeling Probes for UV‐Independent Chemoproteomic Profiling of Carbohydrate–Protein Interactions
1 day ago
Modular carbohydrate-directed labeling probes (CDLPs) convert weak carbohydrate–protein interactions into durable covalent...
Geometric Accommodation of Atom Repulsions Enables Sub‐10 nm Ultra‐Narrowband Multi‐Resonance Blue Emitters
1 day ago
Geometric accommodation by replacing phenyl ring with thiophene alleviates steric H···H repulsion...
Access to Axially Chiral Diaryl Ethers via Catalytic Atroposelective [2+2+2] Cycloaddition of Alkynyloxybenzenes
1 day ago
Despite the scarcity of catalytic asymmetric routes to axially chiral diaryl ethers...
Deaminative Allylation of Primary Amines
1 day ago
Here, we report a deaminative allylation enabled by embedding photoinduced nitrogen-atom deletion...
Deciphering Dynamic Self‐Healing for Crystallinity Control in β‐Ketoenamine‐Linked Covalent Organic Frameworks
1 day ago
A modulator-mediated reversible Michael-addition-elimination (MAE) pathway enables dynamic self-healing, and controllably generates...
Alkali Metal Cation‐Regulated Interfacial Electric Fields Enable Selective C─H Oxidation via Reactive Oxygen Species
1 day ago
In this work, interfacial electric fields are established as a reaction coordinate...
NHC‐Copper(I)‐Mediated Functionalization of White Phosphorus
1 day ago
White phosphorus is functionalized by N-heterocyclic carbene supported copper(I) complexes through redox-neutral...
Environment‐Regulated Crystal‐Structure Reconfiguration of Hybrid Halide Scintillators Enables Tunable STE Emission Toward Intelligent X‐Ray Imaging
1 day ago
An environment-regulated crystal structural reconfiguration strategy enables three structurally distinct single-crystal scintillators...
Intermolecular Interaction‐Facilitated Unimolecular Dehydration of Cyclohexanol on Rutile TiO2(110) Surface
1 day ago
Cyclohexanol dehydration reaction into cyclohexene and water on TiO2 follows an E1cb...
Effect of Structural Similarity Between Dopants and Matrices in Organic Room‐Temperature Phosphorescence Materials: “Like Dissolves Like”
1 day ago
Following the solubility principle “like dissolves like”, structurally matched host–guest systems show...
Access to Unsupported Iminobismuthane and Tetraazabismole Species Enabled by a Rigid and Bulky Organobismuthinidene
1 day ago
By employing a sterically bulky monocoordinate bismuthinidene, the synthesis and characterization of...