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Angewandte Chemie International Edition
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Hydrogen‐Bond‐Induced Switching of Interaction Hierarchy in Dipolar D–A Chromophores for NIR Circularly Polarized Photodetection
1 day ago
Hydrogen-bond-induced switching of interaction hierarchy transforms dipolar donor–acceptor croconaine chromophores from hetero-...
Intergrowth Fluorite Slabs Modulate Interstitial Fluorine to Enhance Fluoride‐Ion Conductivity
1 day ago
Mixed-anion chemistry enables intergrowth fluoroiodides with triple- and quadruple-fluorite slabs, providing a...
Co‐Localization‐Gated Multivalent DNA Logic Gate for Programmable Cell Recognition
1 day ago
The authors report a co-localization-gated DNA logic device assembled from split G-quadruplex...
CO2 as a Redox Shuttle Enables Photocatalytic Dehydrogenative Decarbonylation of Biomass‐Derived Alcohols to Light Alkanes
1 day ago
A heterogeneous photocatalytic system has been developed that enables the dehydrogenative decarbonylation...
A Transiently Activated Rotaxane Mechanocatalyst
1 day ago
The first transient mechanocatalyst based on a [2]rotaxane architecture is demonstrated, showing...
Construction of Axially Chiral Polymers by Asymmetric C–H Activation Polymerization
1 day ago
Despite the increasing numbers of chiral macromolecular systems, incorporating axial chirality into...
Structural and Functional Siderophore Remodeling by Enzymatic Delipidation
1 day ago
A surprising functional switch in bacterial siderophores was discovered through genome mining...
Carbon‐Confined Fe3C/Fe3N Janus Interfaces for Selective Nitric Oxide‐to‐Ammonia Electroreduction
1 day ago
A defect-rich, graphitic-carbon-confined Fe3C/Fe3N Janus catalyst integrates NO transport, adsorption/activation, and interfacial...
Cationic Microenvironment Enhancing Covalent Organic Frameworks for Electrocatalytic CO2 to CH4 Conversion
1 day ago
A cationic microenvironment strategy in tetra-alkylammonium cation-functionalized Cu-Tph-COF-N+ promotes electrocatalytic CO2 to...
One‐Pot Conversion of Acridines Into Phototherapeutic Near‐Infrared Spirocyanines
1 day ago
Integration of a spirocycle into the acridinocyanine backbone is established via one-pot...
Dual Lewis Acid Sites Enabling Passivation‐Resistant Sulfur Oxidation Coupled Hydrogen Evolution Reaction
1 day ago
This work constructs dual Lewis acid sites via Ir─O─Ni bridging coordination on...
Correlating Electronic Transition With Electrical Output to Reveal Photon‐Mediated Energy Conversion Mechanism in Inner‐Shell Electron Battery
1 day ago
By integrating an in-house-developed light-emission detection system for highly charged ions (HCIs)...