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Angewandte Chemie International Edition
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Highly Enantio‐ and Diastereoselective Synthesis of Tetrahydrofuran Frameworks via Chiral Lewis Acid‐Catalyzed Formal [3+2] Cycloaddition of Allylsilanes
1 day ago
The first catalytic asymmetric formal [3+2] cycloaddition of allylsilanes delivers cis-2,5-disubstituted tetrahydrofuran-3-ones...
Na–Fe–P Stoichiometry‐Driven Heterostructure Design With a P2O7‐Rich Buffering Phase for Stable NASICON‐Type Sodium‐Ion Cathodes
1 day ago
An NFPP/N3.12F2.44PO heterostructure is designed to enhance the structural stability of the...
Borate‐Enabled, Scalable Copper Catalysis for Suzuki–Miyaura Cross‐Coupling of Pyridylborons With Unactivated Alkyl Bromides
1 day ago
Described herein is a borate‑enabled copper‑catalyzed Suzuki–Miyaura coupling of challenging pyridylborons with...
Anion‐Managing Biomimetic Electrolyte Based on Fluorinated COF Recognition and Hyperbranched Polyamidoamine Capture for Practical Lithium–Metal Batteries
1 day ago
The composite polymer electrolyte based on covalent organic framework (COF) and hyperbranched...
4‐Mercaptophenylboronic Acid‐Grafted CuO Simultaneously Enhances *CO Adsorption and *H Supply to Boost the Electroreduction of CO2 to C2+ Products
1 day ago
A novel modification strategy using a bifunctional MPBA molecule is reported. An...
Mechanistically Guided Combinatorial Coding Based on Strand Displacement Probes for Multiplex Pathogen Variant Discrimination
1 day ago
A mechanistically guided color-coding strategy enables scalable discrimination of genetic variants with...
[O─I─O]+ Halogen‐Bonded Complexes of Pyridine N‐Oxides
1 day ago
The missing puzzle of 3-center-4-electron halogen-bonded complexes viz. [O─I─O]+ of pyridine N-oxides...
Silicon‐Bridged Homocyclopentadienides: Metal‐Assisted Facile Ring Expansion of Cyclopentadienide by Transient Imino(Metallophosphino)Silylenes
1 day ago
We demonstrate the facile aromatic C─C bond cleavage of cyclopentadienide mediated by...
Supercritical CO2‐Modulated Surface Amorphization and OV Defect in CaSnO3 for High‐Efficiency Electrocatalytic H2O2 Production
1 day ago
In this study, SC CO2 has been used to treat orthorhombic CaSnO3...
Reshaping Chiral Self‐Assemblies Through Alkyne‐Involved Click Chemistry
1 day ago
A Type II topochemical co-assembly was realized, where reaction products reorganize directionally...
Phosphor‐Sensitized Deep Blue Narrowband OLED Devices With EQE Over 40% by Using a Horizontal‐Oriented Host
1 day ago
A horizontal-oriented host with a linear geometry was developed, featuring positive potential...
Low‐Energy Photons in Radical Chemistry: From Deep‐Red to Near‐Infrared Radical Generation for Organic Synthesis
1 day ago
Low-energy photons from deep-red (DR) to near-infrared (NIR) light offer unique opportunities...