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Angewandte Chemie International Edition
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Last updated about 9 hours ago
Direct δ‐Lactone Synthesis From Free Alcohols via Photoinduced δ‐C(sp3)–H Carbonylation in Flow
1 day ago
Herein, we have developed a photo-flow platform for the δ-C(sp3)─H carbonylative lactonization...
A Non‐Covalent [4Fe–4S]/[2Fe] Interface in HydF Guides [FeFe]‐Hydrogenase Maturation
1 day ago
Bridged or not? 57Fe NRVS reveals a non-covalent, electronically coupled interaction between...
Mitochondria‐Targeted Photodynamic Agents Drive Robust Pyroptosis by Caspase‐3/GSDME Activation and Cardiolipin Externalization
1 day ago
We report a series of mitochondria-targeted photodynamic agents that elicit robust pyroptosis...
Bifurcation of *COOH Pathway Determines HCOOH Formation in CO2 Electroreduction on Bismuth
1 day ago
Driven by the mechanistic debate of Bi-catalyzed CO2-to-HCOOH conversion, ambiguity remains regarding...
Asymmetric Reductive Three‐Component Annulation Reaction for Constructing Fused N‐Heterocycles With Contiguous Stereogenic Centers
1 day ago
A chiral phosphoric acid/PhSiH3 system enables reductive three-component annulation of isoquinoliniums, formaldehyde...
Semi‐Ionic C‐F Bonds Modulate Hydrogen Dynamics for Selective CO2‐to‐CH4 Electroreduction on Carbon Quantum Dots
1 day ago
Fluorine-rich carbon quantum dots featuring 28.8 at. % F in semi-ionic C-F...
Transient Polarized Cavities Mediate an Ultrafast and Stable Graphite Anode for Potassium‐Ion Batteries
1 day ago
A dipole-engineered electrolyte forms transient polarized cavities at the K+-graphite interface. These...
Multivalent Antibody‐Recruiting Molecules for Targeted Immune‐Killing of Carbonic Anhydrase IX‐Expressing Cancer Cells
1 day ago
ABSTRACT Antibody clustering on the surface of cells enables recognition by Fc...
Polarity‐Directed Synthesis of an Exfoliable 2D Polyoxometalate‐Based Metal‐Organic Framework for Noble Metal‐Free Alkyne Transfer Semi‐Hydrogenation
1 day ago
Exfoliation of 2D nanosheets based on polyoxometalate metal-organic frameworks (POMOFs) gives access...
Expanding High‐Fidelity Multiplexing in Ultrasensitive Single‐Molecule Protein Detection via Proximity Barcoding
2 days ago
We develop an ultrasensitive, high-accuracy multiplex protein detection platform integrating high-throughput single-molecule...
Lithium‐Germanium Alloy Interfaces for Efficient Low‐Pressure Ammonia Synthesis
2 days ago
We introduce a novel triethylammonium germanate-modified Cu (Cu/TEG) electrode that in situ...
Unlocking a Nitrosuccinate Lyase for Decarboxylative Enzymatic Hydronitration
2 days ago
The nitrosuccinate lyase CreD catalyzes C–NO2 bond formation using nitrite in water...